The draw is due to get under way at 19:00 GMT and will be streamed live across the Women's FA Cup, TNT Sports Football and Channel 4 YouTube channels.
United secured our involvement with a comprehensive 5-0 victory over third-tier side Burnley, in Sunday's fourth-round tie at the Progress With Unity Stadium.
The Reds were ahead inside two minutes after a net-bulging long-range strike from captain Maya Le Tissier got us off to the perfect start in the damp conditions.
That effort seemed to set the tone for the contest, with United not letting control slip from that point on.